Grelha de partida
| A Negro O piloto que efectuou o melhor tempo nos treinos, em itálico o piloto que iniciou a corrida |
| 19 - SpA Ferrari SEFAC John Surtees/Lorenzo Bandini Ferrari 330 P - 3:42.0 (218.286 km/h) |
| 11 - Ford Motor Co. Richie Ginther/Masten Gregory Ford GT 40 - 3:45.3 (215.089 km/h) |
| 15 - North American Racing Team Pedro Rodriguez/Skip Hudson Ferrari 330 P - 3:45.5 (214.898 km/h) |
| 10 - Ford Motor Co. Phil Hill/Bruce McLaren Ford GT 40 - 3:45.9 (214.518 km/h) |
| 14 - Maranello Concessionaires Jo Bonnier/Graham Hill Ferrari 330 P - 3:47.2 (213.290 km/h) |
| 21 - SpA Ferrari SEFAC Mike Parkes/Ludovico Scarfiotti Ferrari 275 P - 3:49.0 (211.614 km/h) |
| 20 - SpA Ferrari SEFAC Jean Guichet/Nino Vaccarella Ferrari 275 P - 3:51.0 (209.782 km/h) |
| 58 - North American Racing Team David Piper/Jochen Rindt Ferrari 250 LM - 3:53.9 (207.181 km/h) |
| 12 - Ford Motor Co. Richard Attwood/Jo Schlesser Ford GT 40 - 3:55.4 (205.861 km/h) |
| 5 - Shelby American Inc Dan Gurney/Bob Bondurant AC Cobra Ford - 3:56.1 (205.250 km/h) |
| 23 - Equipe Nationale Belge Pierre Dumay/Gerhard Langlois van Ophem Ferrari 250 LM - 3:56.4 (204.990 km/h) |
| 22 - SpA Ferrari SEFAC Giancarlo Baghetti/Umberto Maglioli Ferrari 275 P - 3:57.3 (204.212 km/h) |
| 3 - A. C. Cars (of Thames Ditton) Ltd Peter Bolton/Jack Sears AC Coupé Ford - 3:58.2 (203.441 km/h) |
| 18 - Michael Salmon Mike Salmon/Peter Sutcliffe Aston Martin DP 214 (DB4 GTZ) - 3:58.6 (203.100 km/h) |
| 2 - Maserati France Andre Simon/Maurice Trintignant Maserati Tipo 152 - 3:59.5 (202.337 km/h) |
| 1 - Auguste Veuillet Edgar Berney/Pierre Noblet Iso Grifo A3C Chevrolet - 4:01.1 (200.994 km/h) |
| 6 - Briggs S. Cunningham Chris Amon/Jochen Neerpasch AC Cobra Ford - 4:01.3 (200.827 km/h) |
| 30 - Porsche System Engineering Colin Davis/Gerhard Mitter Porsche 904/8 - 4:02.1 (200.164 km/h) |
| 24 - Equipe Nationale Belge Lucien Bianchi/Jean Blaton Ferrari 250 GTO/64 - 4:03.4 (199.094 km/h) |
| 25 - Maranello Concessionaires Innes Ireland/Tony Maggs Ferrari 250 GTO/64 - 4:04.5 (198.199 km/h) |
| 29 - Porsche System Engineering Edgar Barth/Herbert Linge Porsche 904/8 - 4:04.6 (198.118 km/h) |
| 27 - North American Racing Team Fernand Tavano/Bob Grossman Ferrari 250 GTO/64 - 4:04.9 (197.875 km/h) |
| 16 - Peter Lindner Peter Lindner/Peter Nocker Jaguar E-Type "Lightweight" - 4:05.9 (197.070 km/h) |
| 32 - "Franc" Jacques Dewes/Jean Kerguen Porsche 904/4 GTS - 4:14.1 (190.711 km/h) |
| 26 - North American Racing Team Ed Hugus/Jose Rosinski Ferrari 250 GTO/64 - 4:14.1 (190.711 km/h) |
| 34 - Auguste Veuillet Robert Buchet/Guy Ligier Porsche 904/4 GTS - 4:15.6 (189.592 km/h) |
| 17 - P. J. Sargent Peter Sargent/Peter Lumsden Jaguar E-Type "Lightweight" - 4:16.0 (189.295 km/h) |
| 33 - Racing Team Holland Ben Pon/Henk van Zalinge Porsche 904/4 GTS - 4:16.0 (189.295 km/h) |
| 35 - Scuderia Filipinetti Herbert Muller/Claude Sage Porsche 904/4 GTS - 4:17.0 (188.559 km/h) |
| 31 - Porsche System Engineering Heinz Schiller/Gerhard Koch Porsche 904/4 GTS - 4:20.3 (186.168 km/h) |
| 9 - Rootes Group Peter Procter/Jimmy Blumer Sunbeam Tiger Thunderbolt Ford - 4:23.5 (181.225 km/h) |
| 57 - Scuderia S.t Ambroeus Roberto Bussinello/Bruno Deserti Alfa Romeo Giulia TZ - 4:27.4 (178.752 km/h) |
| 41 - Scuderia St. Ambroeus Gianpiero Biscaldi/Giancarlo Sala Alfa Romeo Giulia TZ - 4:31.1 (178.160 km/h) |
| 8 - Rootes Group Claude Dubois/Keith Ballisat Sunbeam Tiger Thunderbolt Ford - 4:32.0 (178.095 km/h) |
| 37 - Bristish Motor Corporation Paddy Hopkirk/Andrew Hedges MG Hardtop BMC - 4:32.1 (176.666 km/h) |
| 46 - Société Automobiles Alpine Henry Morrogh/Roger de Lageneste Alpine M 64 Renault - 4:34.3 (175.578 km/h) |
| 55 - Société Automobiles René Bonnet Jean-Pierre Beltoise/Gerard Laureau René Bonnet Aerodjet Renault - 4:36.0 (174.441 km/h) |
| 40 - Scuderia St. Ambroeus Fernand Masoreo/Jean Rolland Alfa Romeo Giulia TZ - 4:37.8 (174.002 km/h) |
| 38 - Royal Elysées Rene Richard/Pierre Gele Lotus Elan Ford - Lotus - 4:38.5 (172.885 km/h) |
| 54 - Société Automobiles Alpine Philippe Vidal/Henri Grandsire Alpine M 64 Renault - 4:40.3 (170.994 km/h) |
| 64 - Société Chardonnet Regis Fraissinet/Jean de Mortemart AC Cobra Ford - 4:43.4 (170.632 km/h) |
| 47 - Société Automobiles Alpine Mauro Bianchi/Jean Vinatier Alpine M 63 Renault - 4:44.0 (168.087 km/h) |
| 59 - Société Automobiles Alpine Roger Masson/Teodore Zeccoli Alpine M 63 Renault - 4:48.3 (167.738 km/h) |
| 56 - Société Automobiles René Bonnet Pierre Monneret/Jean Claude Rudaz René Bonnet Aerodjet Renault - 4:48.9 (166.071 km/h) |
| 60 - Société Automobiles René Bonnet Bruno Basini/Roland Charriere René Bonnet RB 5 Renault - 4:51.8 (165.787 km/h) |
| 48 - Société Automobiles René Bonnet Robert Bouharde/Prince Michel de Bourbon y Parma René Bonnet Aerodjet Renault - 4:52.3 (164.605 km/h) |
| 43 - Team Elite Clive Hunt/John Wagstaff Lotus Elite (MK 14) Coventry Climax - 4:54.4 (162.072 km/h) |
| 50 - Standard Triumph David Hobbs/Rob Slotemaker Triumph Spitfire - 4:59.0 (158.988 km/h) |
| 42 - Lawrence Tune Engineering Chris Lawrence/Gordon Spice Deep Sanderson 301 BMC - 5:04.8 (158.884 km/h) |
| 53 - Donald Healey Motor Co Ltd. Clive Baker/Bill Bradley Austin-Healey Sprite Sebring - 5:05.0 (458.832 km/h) |
| 49 - Standard Triumph Mike Rothschild/Bob Tullius Triumph Spitfire - 5:05.1 (158.780 km/h) |
| 65 - Standard Triumph Jean-Francois Piot/Jean-Louis Marnat Triumph Spitfire - 5:05.2 (157.285 km/h) |
| 52 - Société Automobiles René Bonnet Philippe Farjon/Serge Lelong René Bonnet Aerodjet Renault - 5:08.1 (153.450 km/h) |
| 44 - Société d'Etudes et Const (SECA) C. D. Alain Bertaut/Andre Guilhaudin CD LM64 Panhard - 5:15.8 (151.059 km/h) |
| 45 - Société d'Etudes et Const (SECA) C. D. Pierre Lelong/Guy Verrier CD LM64 Panhard - 5:20.8 (149.798 km/h) |
